2,2,6,6-四甲基-3,5-庚二酮（TMHD）金属化合物

2,2,6,6-四甲基-3,5-庚二酮（TMHD）不溶于水（0.02g/100mL），是一种高效萃取溶剂。铕和镨与TMHD形成的螯合物可用做NMR位移试剂，在GC分析试验中可分析Al,Be,Cr和稀土金属。同时，TMHD作为配体备受青睐。它与多种金属形成的金属配合物，可以用作MOCVD前驱体和均相反应的催化剂，并能有效提高苛刻条件反应（如Ullmann反应）收率。

美国STREM工厂提供各种高纯度、品质卓越的2,2,6,6-四甲基-3,5-庚二酮金属化合物，满足不同研究领域需求。

2008 年百灵威与STREM 正式签署战略合作协议，全权负责STREM 在中国市场的产品销售、技术应用与支持等各项业务。百灵威始终秉承“资源共享，共同发展”之理念，一如既往地为中国化学行业广大科研和生产用户提供品质卓越的有机金属、配体、催化剂等产品及服务！

metals • inorganics • organometallics • catalysts • ligands • customsynthesis • cGMP facilities • nanomaterials

● Aluminum ● Europium ● Molybdenum ● Scandium
● Barium ● Gadolinium ● Neodymium ● Silver
● Bismuth ● Gallium ● Nickel ● Strontium
● Calcium ● Holmium ● Niobium ● Terbium
● Cerium ● Indium ● Oxygen ● Thallium
● Cesium ● Iron ● Palladium ● Thulium
● Chromium ● Lanthanum ● Potassium ● Titanium
● Cobalt ● Lead ● Praseodymium ● Ytterbium
● Copper ● Lithium ● Rubidium ● Yttrium
● Dysprosium ● Magnesium ● Ruthenium ● Zinc
● Erbium ● Manganese ● Samarium ● Zirconium
13-5000 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)aluminum, 99% (99.9%-Al) [Al(TMHD)3] [14319-08-5]
Al(C11H19O2)3; FW: 576.80; white xtl.; m.p. 255-258°; b.p. dec. >400° (subl. 150°/0.01mm) 1g
5g
25g
56-8500
HAZ Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)barium hydrate [Ba(TMHD)2] [17594-47-7]
Ba(C11H19O2)2·XH2O; FW: 503.85; white pwdr.; m.p. 195-200°; b.p. dec. 285° (subl. 225°/0.05mm) moisture sensitive 1g
5g
25g
83-1000 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)bismuth(III), min. 98% (99.9%-Bi)
[Bi(TMHD)3] [142617-53-6]
Bi(C11H19O2)3; FW: 758.74; off-white xtl.; m.p. 114-116°; b.p. dec. 295° (subl. 150°/0.05mm) 1g
5g
25g
20-1000 Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)calcium [Ca(TMHD)2] [36818-89-0]
Ca(C11H19O2)2; FW: 406.62; white pwdr.; m.p. 220-223°; b.p. dec. 280° (subl. 205°/0.1mm) 1g
5g
25g
58-5000 Tetrakis(2,2,6,6-tetramethyl-3,5-heptanedionato)cerium(IV), min. 97% (99.9%-Ce) (REO) [Ce(TMHD)4][18960-54-8]
Ce(C11H19O2)4; FW: 873.20; red pwdr.; m.p. 275-280°; b.p. dec. 295° (subl. 140°/0.05mm) 1g
5g
25g
55-5000 2,2,6,6-Tetramethyl-3,5-heptanedionato cesium [Cs(TMHD)] [61346-75-6]
CsC11H19O2; FW: 316.18; pale yellow pwdr. 1g
5g
24-1500 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)chromium(III), 99% [Cr(TMHD)3] [14434-47-0]
Cr(C11H19O2)3; FW: 601.82; purple xtl.; m.p. 230-232°; b.p. dec. 270° 1g
5g
27-3000 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)cobalt(III), 99% (99.9+%-Co) [Co(TMHD)3] [14877-41-9]
Co(C11H19O2)3; FW: 608.74; green pwdr.; m.p. 254-256°; b.p. 250° dec. (subl. 120°/0.5mm) 1g
5g
25g
29-3000 Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)copper(II), 99% [Cu(TMHD)2] [14040-05-2]
Cu(C11H19O2)2; FW: 430.05; blue xtl.; m.p. 198°; b.p. dec. 315° (subl. 88°/0.05mm) 1g
5g
25g
66-8500 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)dysprosium(III), 98+% (99.9%-Dy) (REO) [Dy(TMHD)3] [15522-69-7]
Dy(C11H19O2)3; FW: 712.31; off-white xtl.; m.p. 182-185°; b.p. dec. 265° hygroscopic 1g
5g
68-8750 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)erbium(III), 99% (99.9%-Er) (REO) [Er(TMHD)3]
[35733-23-4]
Er(C11H19O2)3; FW: 717.08; pink xtl.; m.p. 168-171°; b.p. dec. 345° (subl. 160°/0.1mm) 1g
5g
25g
93-6328 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III), 99% (99.9%-Eu) (REO) [Eu(TMHD)3]
[15522-71-1]
Eu(C11H19O2)3; FW: 701.78; yellow pwdr.; m.p. 188-189°; b.p. dec. 275° 1g
5g
64-5000 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)gadolinium(III), 99%(99.9%-Gd) (REO) [Gd(TMHD)3]
[14768-15-1]
Gd(C11H19O2)3; FW: 707.07; off-white xtl.; m.p. 178-183°; b.p. dec. 295° 1g
5g
31-5000 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)gallium(III), 99% (99.999%-Ga) [Ga(TMHD)3]PURATREM
[34228-15-4]
Ga(C11H19O2)3; FW: 619.54; white xtl.; m.p. 219-220°; b.p. dec. 360° (subl. 170°/0.2mm) 1g
5g
25g
67-5000 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)holmium(III), 99% (99.9%-Ho) (REO) [Ho(TMHD)3]
[15522-73-3]
Ho(C11H19O2)3; FW: 714.75; off-white xtl.; m.p. 179-181°; b.p. dec. 290° 1g
5g
49-2200 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)indium(III), 99% (99.9%-In) [In(TMHD)3] [34269-03-9]
In(C11H19O2)3; FW: 664.63; white to off-white pwdr.; m.p. 167° 1g
5g
26-3910 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)iron(III), 99% (99.9%-Fe) [Fe(TMHD)3] [14876-47-2]
Fe(C11H19O2)3; FW: 605.66; red xtl.; m.p. 164°; b.p. dec. 300° 1g
5g
25g
57-1000 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)lanthanum(III), 99% (99.9%-La) (REO) [La(TMHD)3]
[14319-13-2]
La(C11H19O2)3; FW: 688.72; white pwdr.; m.p. 227-231°; b.p. dec. 370° (subl. 210°/0.2mm) 1g
5g
25g
82-2100 Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)lead(II), 99% [Pb(TMHD)2] [21319-43-7]
Pb(C11H19O2)2; FW: 573.75; white pwdr.; m.p. 126-128°; b.p. 325° dec. (subl. 134°/0.1mm) 1g
5g
25g
03-5001 2,2,6,6-Tetramethyl-3,5-heptanedionato lithium, 98+% [Li(TMHD)] [22441-13-0]
LiC11H19O2; FW: 190.24; white pwdr.; m.p. 265-268°; b.p. dec. 295° 1g
5g
25g
12-0900 Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)magnesium, anhydrous, min. 98% [Mg(TMHD)2]
[21361-35-3]
Mg(C11H19O2)2; FW: 390.85; white pwdr. hygroscopic 1g
5g
12-1000 Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)magnesium dihydrate, min. 98% [Mg(TMHD)2] [21361-35-3]
Mg(C11H19O2)2·2H2O; FW: 390.85 (426.88); white pwdr.; m.p. 135-150° (-H2O); b.p. dec. 290° (subl. 150°/0.05mm) 1g
5g
25g
25-5000 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III), 99% [Mn(TMHD)3] [14324-99-3]
Mn(C11H19O2)3; FW: 604.74; black xtl.; m.p. 165°; b.p. dec. 255° 1g
5g
25g
42-1357 Molybdenum(VI) dioxide bis(2,2,6,6-tetramethyl-3,5-heptanedionate), min. 98% [O2Mo(TMHD)2]
[34872-98-5]
MoO2(C11H19O2)2; FW: 494.48; yellow xtl.; m.p. 129-131° moisture sensitive 1g
5g
25g
60-8750 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)neodymium(III), 99% (99.9%-Nd) (REO) [Nd(TMHD)3] [15492-47-4]
Nd(C11H19O2)3; FW: 694.06; light purple xtl.; m.p. 209-212°; b.p. dec. 270° (subl. 150°/0.1mm) 1g
5g
28-0088 Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)nickel(II), min. 98% (99.9%-Ni) [Ni(TMHD)2] [41749-92-2]
Ni(C11H19O2)2; FW: 425.23; purple xtl.; m.p. 223-225°; b.p. subl. 90-110°/0.1mm hygroscopic 1g
5g
25g
41-7000 Tetrakis(2,2,6,6-tetramethyl-3,5-heptanedionato)niobium(IV), 99% [Nb(TMHD)4] [41706-15-4]
Nb(C11H19O2)4; FW: 826.00; black xtl.; m.p. 219-220°; b.p. dec. 325° 1g
5g
25g
08-2050 2,2,6,6-Tetramethylheptane-3,5-dione, 98% TMHD [1118-71-4]
(CH3)3CC(O)CH2C(O)C(CH3)3; FW: 184.28; colorless to pale yellow liq.; b.p. 72-73°/6 mm; f.p. 153°F; d. 0.883 1g
5g
25g
46-0248 Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)palladium(II), min. 98% [Pd(TMHD)2] [15214-66-1]
Pd(C11H19O2)2; FW: 472.95; orange pwdr. 1g
5g
19-6000 2,2,6,6-Tetramethyl-3,5-heptanedionato potassium, min. 95% [K(TMHD)] [22441-14-1]
KC11H19O2; FW: 222.40; light brown pwdr.; b.p. dec. 150° hygroscopic 1g
5g
25g
93-5937 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)praseodymium(III), 99% (99.9%-Pr) (REO) [Pr(TMHD)3] [15492-48-5]
Pr(C11H19O2)3; FW: 690.72; light green pwdr.; m.p. 212-214°; b.p. dec. 300° (subl. 150°/0.1mm) 1g
5g
37-5000 2,2,6,6-Tetramethyl-3,5-heptanedionato rubidium [Rb(TMHD)] [166439-15-2]
RbC11H19O2; FW: 268.74; white to off-white pwdr. 1g
5g
25g
44-8000 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ruthenium(III), 99% (99.9%-Ru) [Ru(TMHD)3] [38625-54-6]
Ru(C11H19O2)3; FW: 650.88; orange pwdr.; m.p. 210-213°; b.p. dec. 250° (subl. 120°/0.5mm) 1g
5g
62-4000 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)samarium(III) (99.9%-Sm) (REO) [Sm(TMHD)3] [15492-50-9]
Sm(C11H19O2)3; FW: 700.11; pale yellow xtl.; m.p. 191-193°; b.p. dec. 250° (subl. 183°/1.3mm) 1g
5g
21-1000 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)scandium(III), 99% (99.9%-Sc) (REO) [Sc(TMHD)3]
[15492-49-6]
Sc(C11H19O2)3; FW: 594.77; white pwdr.; m.p. 150-152°; b.p. dec. 275° 500mg
2g
47-2600 2,2,6,6-Tetramethyl-3,5-heptanedionato silver(I) (99.9%-Ag) [Ag(TMHD)] [79827-25-1]
AgC11H19O2; FW: 291.14; gray pwdr.; m.p. 178° dec. 1g
5g
25g
38-1000 Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)strontium hydrate [Sr(TMHD)2] [199445-30-2]
Sr(C11H19O2)2·XH2O; FW: 454.16; light yellow pwdr.; m.p. 200-203°; b.p. dec. 250° (subl. 230°/0.05mm) 1g
5g
25g
65-8000 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)terbium(III), 99% (99.9%-Tb) (REO) [Tb(TMHD)3]
[15492-51-0]
Tb(C11H19O2)3; FW: 708.74; off-white xtl.; m.p. 155-156°; b.p. dec. 275° 1g
5g
81-1000
HAZ 2,2,6,6-Tetramethyl-3,5-heptanedionato thallium(I), 99% [Tl(TMHD)] [56713-38-3]
Tl(C11H19O2); FW: 387.62; off-white xtl.; m.p. 159-164°; b.p. dec. 260° (subl. 110°/0.1mm) 1g
5g
69-7000 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)thulium(III), 98% (99.9%-Tm) (REO) [Tm(TMHD)3]
[15631-58-0]
Tm(C11H19O2)3; FW: 718.75; off-white xtl.; m.p. 169-172°; b.p. dec. 280° 1g
5g
22-0340 Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)oxotitanium(IV), min. 95% [OTi(TMHD)2] [152248-67-4]
OTi(C11H19O2)2; FW: 430.42; off-white pwdr.; m.p. 120° dec. 500mg
2g
10g
22-6000
amp Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)titanium(III), min. 97% [Ti(TMHD)3] [181418-64-4]
Ti(C11H19O2)3; FW: 597.70; purple xtl.; b.p. subl. 75°/0.1mm air sensitive 1g
5g
25g
70-0100 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ytterbium(III), 99% (99.9%-Yb) (REO) [Yb(TMHD)3]
[15492-52-1]
Yb(C11H19O2)3; FW: 722.86; off-white xtl.; m.p. 167-169°; b.p. dec. 300° 1g
5g
39-1000 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)yttrium(III), 98+% (99.9%-Y) (REO) [Y(TMHD)3]
[15632-39-0]
Y(C11H19O2)3; FW: 638.72; white to off-white xtl.; m.p. 170-173°; b.p. dec. 290° (subl. 95°/0.05mm) 1g
5g
25g
30-0500 Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)zinc, 99% [Zn(TMHD)2] [14363-14-5]
Zn(C11H19O2)2; FW: 431.93; white xtl.; m.p. 144°; b.p. dec. 250° 1g
5g
25g
40-5000 Tetrakis(2,2,6,6-tetramethyl-3,5-heptanedionato)zirconium(IV), 99% [Zr(TMHD)4] [18865-74-2]
Zr(C11H19O2)4; FW: 824.30; white xtl.; m.p. 318-320°; b.p. subl. 180°/0.1mm 1g
5g
25g